Fluorinated carbonates as new diluents for extraction and separation of f-block elements

Distler, P., Mindová, M., John, J., Babain, V. A., Alyapyshev, M. Y., Tkachenko, L. I., Kenf, E. V., Harwood, L. M. ORCID: https://orcid.org/0000-0002-8442-7380 and Afsar, A. (2020) Fluorinated carbonates as new diluents for extraction and separation of f-block elements. Solvent Extraction and Ion Exchange, 38 (2). pp. 180-193. ISSN 1532-2262 doi: 10.1080/07366299.2019.1708004

Abstract/Summary

The fluorinated carbonate BK-1 solvent was studied as a diluent in extraction systems with different extracting agents – CMPO, THDGA, CyMe4-BTBP, and CyMe4-BTPhen, which are the most promising molecules for separation of minor actinides and lanthanides. Dependence of the extraction properties of the system on the concentrations of HNO3 or extracting compound, kinetics of trivalent metal extraction and extraction of the ions by neat diluent (without the addition of extracting agent) were investigated. Based on the obtained results, BK-1 is a promising candidate diluent for f-block metal separation.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/88704
Item Type	Article
Refereed	Yes
Divisions	Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Uncontrolled Keywords	General Chemistry, General Chemical Engineering
Publisher	Informa UK Limited
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