Thermodynamic parameters of Am(III), Cm(III) and Eu(III) extraction by CyMe4-BTPhen in cyclohexanone from HNO3 solutions

Distler, P., Stamberg, K., John, J., Harwood, L. M. ORCID: https://orcid.org/0000-0002-8442-7380 and Lewis, F. W. (2020) Thermodynamic parameters of Am(III), Cm(III) and Eu(III) extraction by CyMe4-BTPhen in cyclohexanone from HNO3 solutions. Journal of Chemical Thermodynamics, 141. 105955. ISSN 0021-9614 doi: 10.1016/j.jct.2019.105955

Abstract/Summary

The thermodynamic parameters of the extraction system consisting of CyMe4-BTPhen dissolved in cyclohexanone and Am(III), Cm(III) and Eu(III) in HNO3 in the aqueous phase have been determined. Kinetic extraction experiments were carried out under various temperatures (15 – 45 °C) and the corresponding over-all mass transfer coefficients were used for the calculation of apparent activation energy and frequency factor values. The values of reaction enthalpy and entropy were also calculated using the distribution coefficients resulting from the experiments mentioned above. Based on the calculated data, the rate-controlling processes and the exothermic character of the studied extractions were determined.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/86832
Identification Number/DOI	10.1016/j.jct.2019.105955
Refereed	Yes
Divisions	Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher	Elsevier
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