Crystallization and lamellar nanosheet formation of an aromatic dipeptoid

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Castelletto, V., Chippindale, A. M. orcid id iconORCID: https://orcid.org/0000-0002-5918-8701, Hamley, I. W. orcid id iconORCID: https://orcid.org/0000-0002-4549-0926, Barnett, S., Hasan, A. and Lau, K. H. A. (2019) Crystallization and lamellar nanosheet formation of an aromatic dipeptoid. Chemical Communications, 55. pp. 5867-5869. ISSN 1359-7345 doi: 10.1039/C9CC02335F

Abstract/Summary

An aromatic peptoid analogue of the diphenylalanine dipeptide self-assembles in aqueous solution and the first crystal structure was obtained for this class of compound. This reveals molecular packing stabilized by networks of hydrogen bonds. Free-floating nanosheet lamellar structures are observed in solution, which form via cooperative intermolecular interactions driven by π stacking.

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Item Type Article
URI https://reading-clone.eprints-hosting.org/id/eprint/83535
Identification Number/DOI 10.1039/C9CC02335F
Refereed Yes
Divisions Interdisciplinary centres and themes > Chemical Analysis Facility (CAF)
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher Royal Society of Chemistry
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