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The v2, v5 Raman band system of 13CH3F

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Hegelund, F., Brodersen, S. and Mills, I. (1978) The v2, v5 Raman band system of 13CH3F. Journal of Molecular Spectroscopy, 70 (3). pp. 386-393. ISSN 0022-2852 doi: 10.1016/0022-2852(78)90176-5

Abstract/Summary

The anisotropic and isotropic components of the ν2, ν5 rotation-vibrational Raman bands of 13CH3F were obtained separately. The two upper states are coupled by a strong second-order Coriolis resonance. The anisotropic spectrum was analyzed by means of a program system due to R. Escribano. A contour simulation and a least-squares fit of 233 assigned transitions yielded values for ν5, ΔA5, ΔA2, and Aζ5a, 5b(z). The 13C shifts of ν2 and ν5 were obtained from the isotropic spectrum.

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Item Type Article
URI https://reading-clone.eprints-hosting.org/id/eprint/7569
Item Type Article
Refereed Yes
Divisions Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher Academic Press
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