Anharmonicity and local mode effects in the vibrational spectrum of NiCO4 and Co(CO)3NO

Mills, I. (1987) Anharmonicity and local mode effects in the vibrational spectrum of NiCO4 and Co(CO)3NO. Journal of Molecular Physics, 61 (3). pp. 711-724. ISSN 0026-8976 doi: 10.1080/00268978700101411

Abstract/Summary

Previously published data on the vibrational fundamentals and overtones of the carbonyl stretching modes of Ni(CO)4 and Co(CO)3NO are reinterpreted using the recent model of Mills and Robiette, including Darling-Dennison resonances and local mode effects. The harmonic wavenumber θm and anharmonicity constant xm associated with the carbonyl and nitrosyl stretching modes are derived, and the 13C and 18O isotopic shifts are discussed in relation to the harmonic and anharmonic force field.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/7459
Item Type	Article
Refereed	Yes
Divisions	Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher	Taylor and Francis
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