Vibration-rotation spectra and the harmonic force field of HOCl

Deeley, C. M. and Mills, I. (1985) Vibration-rotation spectra and the harmonic force field of HOCl. Journal of Molecular Spectroscopy, 114 (2). pp. 368-376. ISSN 0022-2852 doi: 10.1016/0022-2852(85)90232-2

Abstract/Summary

Vibration-rotation spectra of HOCl have been measured at a resolution of 0.05 cm−1 to determine vibration rotation constants, and 35–37 Cl isotope shifts in the vibration frequencies. The spectrum of DOCl has also been recorded, and a preliminary analysis for the band origins has been made. The vibrational frequency data and centrifugal distortion constants have been used to determine the harmonic force field in a least-squares refinement; the force field obtained also gives a good fit to data on the vibrational contributions to the inertial defect. The equilibrium rotational constants of HOCl have been obtained, and an equilibrium structure has been estimated.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/7433
Item Type	Article
Refereed	Yes
Divisions	Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher	Academic Press
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