Extraction of minor actinides, lanthanides and other fission products by silica-immobilized BTBP/BTPhen ligands

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Afsar, A., Distler, P., Harwood, L. M. orcid id iconORCID: https://orcid.org/0000-0002-8442-7380, John, J. and Westwood, J. (2017) Extraction of minor actinides, lanthanides and other fission products by silica-immobilized BTBP/BTPhen ligands. Chemical Communications, 53 (28). pp. 4010-4013. ISSN 1359-7345 doi: 10.1039/c7cc01286a

Abstract/Summary

Novel BTBP [bis-(1,2,4-triazin-3-yl)-2,2’-bipyridine] / BTPhen [bis-(1,2,4-triazin-3-yl)-1,10-phenanthroline] functionalized silica gels have been developed to extract minor actinides, lanthanides and other fission products. BTPhen functionalized silica gel is capable of near-quantitative removal of Am(III) in the presence of Eu(III) from aqueous HNO3, while BTBP functionalized silica gel is able to remove problematic corrosion and fission products that are found in PUREX raffinates.

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Item Type Article
URI https://reading-clone.eprints-hosting.org/id/eprint/69930
Identification Number/DOI 10.1039/c7cc01286a
Refereed Yes
Divisions Interdisciplinary centres and themes > Chemical Analysis Facility (CAF)
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher The Royal Society of Chemistry
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