Laboratory kinetic studies of the reactions of Cl atoms with species of biogenic origin: δ3-Carene, isoprene, methacrolein and methyl vinyl ketone

Canosa-Mas, C. E., Hutton-Squire, H. R., King, M. D., Stewart, D. J., Thompson, K. C. and Wayne, R. P. (1999) Laboratory kinetic studies of the reactions of Cl atoms with species of biogenic origin: δ3-Carene, isoprene, methacrolein and methyl vinyl ketone. Journal of Atmospheric Chemistry, 34 (1). pp. 163-170. ISSN 1573-0662 doi: 10.1023/A:1006214423298

Abstract/Summary

The rate coefficients for the reaction between atomic chlorine and a number of naturally occurring species have been measured at ambient temperature and atmospheric pressure using the relative rate technique. The values obtained were (4.0 ± 0.8) × 10-10, (2.1 ± 0.5) × 10-10, (3.2 ± 0.5) × 10-10, and (4.9 ± 0.5) × 10-10 cm3 molecule-1 s-1, for reactions with isoprene, methyl vinyl ketone, methacrolein and δ3-carene, respectively. The value obtained for isoprene compares favourably with previously reported values. No values have been reported to date for the rate constants of the other reactions.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/5977
Item Type	Article
Refereed	Yes
Divisions	No Reading authors. Back catalogue items
Uncontrolled Keywords	δ3-carene, chlorine atoms,isoprene, kinetics, methacrolein and methyl vinyl ketone
Publisher	Springer
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