Synthesis and characterization of inorganic-organic hybrid gallium selenides

Ewing, S. J. and Vaqueiro, P. ORCID: https://orcid.org/0000-0001-7545-6262 (2014) Synthesis and characterization of inorganic-organic hybrid gallium selenides. Inorganic Chemistry, 53 (17). pp. 8845-8847. ISSN 1520-510X doi: 10.1021/ic5011314

Abstract/Summary

Two semiconducting hybrid gallium selenides, [Ga6Se9(C6H14N2)4][H2O] (1) and [C6H14N2][Ga4Se6(C6H14N2)2] (2), were prepared using a solvothermal method in the pres-ence of 1,2-diaminocyclohexane (1,2-DACH). Both materials consist of neutral inorganic layers, in which 1,2-DACH is co-valently bonded to gallium. In (1), the organic amine acts as a monodentate and a bidentate ligand, while in (2) bidentate and uncoordinated 1,2-DACH molecules coexist.

Additional Information	Manuscript accepted, but not yet published online
Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/37393
Identification Number/DOI	10.1021/ic5011314
Refereed	Yes
Divisions	Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Additional Information	Manuscript accepted, but not yet published online
Publisher	American Chemical Society
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