Unusual reactivity of [Os3Sn(.mu.-H)2(CO)10R2] involving the tin atom and the novel bridging hydride: x-ray crystal and molecular structures of [Os3Sn(.mu.-H)2{.mu.-RC(Os)(:O)(Sn)}(CO)9R] and [Os3Sn(CO)9{.mu.2,.eta.1-C(CO2Me)CH2C:O(Os)OMe}R2] [R = CH(SiMe3)2]

Cardin, C. J. ORCID: https://orcid.org/0000-0002-2556-9995, Cardin, D. J., Power, J. M. and Hursthouse, M. B. (1985) Unusual reactivity of [Os3Sn(.mu.-H)2(CO)10R2] involving the tin atom and the novel bridging hydride: x-ray crystal and molecular structures of [Os3Sn(.mu.-H)2{.mu.-RC(Os)(:O)(Sn)}(CO)9R] and [Os3Sn(CO)9{.mu.2,.eta.1-C(CO2Me)CH2C:O(Os)OMe}R2] [R = CH(SiMe3)2]. Journal of the American Chemical Society, 107 (2). pp. 505-507. ISSN 0002-7863 doi: 10.1021/ja00288a041