Melt brushes of diblock copolymer

Matsen, M. W. and Griffiths, G. H. ORCID: https://orcid.org/0009-0002-6340-3686 (2009) Melt brushes of diblock copolymer. European Physical Journal E, 29 (2). pp. 219-227. ISSN 1292-8941 doi: 10.1140/epje/i2009-10470-2

Abstract/Summary

Using self-consistent field theory (SCFT), we investigate the morphologies formed by a melt brush of AB diblock copolymers grafted to a flat substrate by their B ends. In addition to a laterally uniform morphology, SCFT predicts three ordered morphologies exhibiting different periodic patterns at the air surface: a hexagonal array of A-rich dots, an alternating sequence of A- and B-rich stripes, and a hexagonal pattern of B-rich dots. When the phase diagram of the tethered film is plotted as a function of A/B incompatibility, $\chi N$, and diblock composition, $f$, it resembles the bulk phase diagram with the periodic phases converging to a mean-field critical point at weak segregation. The periodic-phase region in the phase diagram shrinks with increasing grafting density and expands when the air surface acquires an affinity for the grafted B blocks.