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Syntheses of ethyl 3-deoxy-3,3-difluoro-D-arabino-heptulosonate and analogues

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Li, Y., Drew, M.G.B., Welchman, E.V., Shirvastava, R.K., Jiang, S.D., Valentine, R. and Singh, G. (2004) Syntheses of ethyl 3-deoxy-3,3-difluoro-D-arabino-heptulosonate and analogues. Tetrahedron, 60 (31). pp. 6523-6531. ISSN 0040-4020 doi: 10.1016/j.tet.2004.06.048

Abstract/Summary

The difluormated analogues of 3-deoxy-D-arabino-heptulosonic acid (DAH) 12, 24 and its enantiomer have been synthesised from D- and L-crythrose via a Reformatsky reaction which gave a mixture of diastereoiosmers in favour of the anti isomer. (C) 2004 Elsevier Ltd. All rights reserved.

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Item Type Article
URI https://reading-clone.eprints-hosting.org/id/eprint/11429
Identification Number/DOI 10.1016/j.tet.2004.06.048
Refereed Yes
Divisions Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Uncontrolled Keywords Reformatsky reaction, shikimate pathway, carbohydrate, fluorinated ulosonatm, enzyme inhibitors , SHIKIMATE PATHWAY, APICOMPLEXAN PARASITES, ACID, SYNTHASE, NUCLEOSIDES, DERIVATIVES
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