Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti-III/Ti-IV

Chippindale, A.M. ORCID: https://orcid.org/0000-0002-5918-8701, Grimshaw, M.R., Powell, A.V. and Cowley, A.R. (2005) Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti-III/Ti-IV. Inorganic Chemistry, 44 (12). pp. 4121-4123. ISSN 0020-1669 doi: 10.1021/ic050399y

Abstract/Summary

The first 3-D open-framework TiGaPO complex, constructed from (TiO6)-O-III, (TiO6)-O-IV, GaO4, and PO4 polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure.