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Matsen, M. W. (2007) Polydispersity-induced macrophase separation in diblock copolymer melts. Physical Review Letters, 99. p. 148304. doi: 10.1103/PhysRevLett.99.148304
Abstract/Summary
The effect of A-block polydispersity on the phase behavior of AB diblock copolymer melts is examined using a complete self-consistent field theory treatment that allows for fractionation of the parent molecular-weight distribution. In addition to observing the established shift in phase boundaries, we find the emergence of significant two-phase coexistence regions causing, for instance, the disappearance of the complex phase window. Furthermore, we find evidence that polydispersity relieves packing frustration, which will reduce the tendency for long-range order.
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| Item Type | Article |
| URI | https://reading-clone.eprints-hosting.org/id/eprint/769 |
| Item Type | Article |
| Refereed | Yes |
| Divisions | Science > School of Mathematical, Physical and Computational Sciences > Department of Mathematics and Statistics |
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