The high-resolution infrared spectrum of HOF near 2700 cm-1: the ground and 2v2 states

Bürger, H., Pawelke, G., Sommer, S., Rahner, A., Appelman, E. H. and Mills, I. (1989) The high-resolution infrared spectrum of HOF near 2700 cm-1: the ground and 2v2 states. Journal of Molecular Spectroscopy, 136 (1). pp. 197-204. ISSN 0022-2852 doi: 10.1016/0022-2852(89)90232-4

Abstract/Summary

The a/b hybrid-type ν1 fundamental and 2ν2 overtone bands of HOF were investigated by FTIR spectroscopy with a resolution close to 0.008 cm−1. Improved ground state parameters of HOF were determined from a merge of more than 3000 ground state combination differences formed from ν1 and previously measured ν2 transitions with the reported pure rotational lines. Excited state parameters of the v2 = 2 state, ν0 = 2686.924 6(1) and χ22 = −9.942 4(1) cm−1, were determined employing Watson's A-reduced Hamiltonian up to sixth order in I′ representation. The 2ν2 state was found to be unperturbed, the excited state parameters being closely related to those of ν2.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/7579
Item Type	Article
Refereed	Yes
Divisions	Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher	Academic Press
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