Efficient access to conjugated 4,4’-bipyridinium oligomers using the Zincke reaction: synthesis, spectroscopic and electrochemical properties

Chen, L., Willcock, H., Wedge, C. J., Hartl, F. ORCID: https://orcid.org/0000-0002-7013-5360, Colquhoun, H. M. and Greenland, B. W. (2016) Efficient access to conjugated 4,4’-bipyridinium oligomers using the Zincke reaction: synthesis, spectroscopic and electrochemical properties. Organic and Biomolecular Chemistry, 14 (3). pp. 980-988. ISSN 1477-0520 doi: 10.1039/c5ob02211h

Abstract/Summary

The cyclocondensation reaction between rigid, electron-rich aromatic diamines and 1,1′-bis(2,4-dinitrophenyl)-4,4′-bipyridinium (Zincke) salts has been harnessed to produce a series of conjugated oligomers containing up to twelve aromatic/heterocyclic residues. These oligomers exhibit discrete, multiple redox processes accompanied by dramatic changes in electronic absorption spectra.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/48398
Identification Number/DOI	10.1039/c5ob02211h
Refereed	Yes
Divisions	Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry Life Sciences > School of Chemistry, Food and Pharmacy > School of Pharmacy > Medicinal Chemistry Research Group
Publisher	Royal Society of Chemistry
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