Synthesis, x-ray structure and anion binding properties of a cryptand-like hybrid calixpyrrole

Cafeo, G., Colquhoun, H. M., Cuzzola, A., Gattuso, M., Kohnke, F. H., Valenti, L. and White, A. J. P. (2010) Synthesis, x-ray structure and anion binding properties of a cryptand-like hybrid calixpyrrole. Journal of Organic Chemistry, 75 (18). pp. 6263-6266. ISSN 1520-6904 doi: 10.1021/jo1010262

Abstract/Summary

The novel cryptand in/out-3, containing two tripyrrolemethane units briged by three 1,3- diisopropylidenbenzene arms was readily synthesized by a convergent three-step synthesis. It binds fluoride by inclusion with excellent selectivity with respect to a number of other tested anions. The structure of the free receptor and that of its fluoride complex were investigated in solution by NMR spectroscopy. The solid state X-ray structure of the free cryptand 3 was also determined.

Item Type	Article
URI	https://reading-clone.eprints-hosting.org/id/eprint/16568
Identification Number/DOI	10.1021/jo1010262
Refereed	Yes
Divisions	Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Publisher	American Chemical Society
Download/View statistics	View download statistics for this item