Advanced search

Preparation and ring-opening reactions of N,O-bis(diphenylphosphinyl) hydroxymethylaziridine ('Di-Dpp')

Download
Full text not archived in this repository.
Advice

Please see our End User Agreement.

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

Tools
Add to AnyAdd to TwitterAdd to FacebookAdd to LinkedinAdd to PinterestAdd to Email
Lists

Sweeney, J.B. and Cantrill, A.A. (2003) Preparation and ring-opening reactions of N,O-bis(diphenylphosphinyl) hydroxymethylaziridine ('Di-Dpp'). Tetrahedron, 59 (21). pp. 3677-3690. ISSN 0040-4020 doi: 10.1016/s0040-4020(03)00551-9

Abstract/Summary

N,O-bis(diphenylphosphinyl)-2-(hydroxymethyl)aziridine ('DiDpp', 1) is efficiently prepared from 2-aminoethane-1,3-diol: this activated aziridine undergoes two sequential reactions with copper(I)-modified Grignard reagents, yielding alpha-branched N-Dpp amines in good yield. (C) 2003 Elsevier Science Ltd. All rights reserved.

Altmetric Badge

Item Type Article
URI https://reading-clone.eprints-hosting.org/id/eprint/11644
Identification Number/DOI 10.1016/s0040-4020(03)00551-9
Refereed Yes
Divisions Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Uncontrolled Keywords aziridinemethanol, ring-opening, phosphinate, 2,3-EPOXY AMINES, REARRANGEMENT, 2-AZIRIDINEMETHANOLS, AZIRIDINES
Download/View statistics View download statistics for this item
Deposit Details

University Staff: Request a correction | Centaur Editors: Update this record

Search Google Scholar