1,4,8,11-tetraazacyclotetradecane antimony(III) sulfide

Lees, R.J.E., Powell, A.V., Watkin, D.J. and Chippindale, A.M. ORCID: https://orcid.org/0000-0002-5918-8701 (2007) 1,4,8,11-tetraazacyclotetradecane antimony(III) sulfide. Acta Crystallographica Section C-Crystal Structure Communications, 63 (1). M27-M29. ISSN 0108-2701 doi: 10.1107/s010827010605044x

Abstract/Summary

Poly[1,4,8,11-tetraazacyclotetradecane(2+) [hepta-mu-sulfidotrisulfidohexaantimony(III)]], {(C10H26N4)[Sb6S10]}(n), consists of novel [Sb6S10](2). layers containing Sb2S2, Sb4S4 and Sb7S7 hetero-rings, which are separated by macrocyclic amine molecules. The macrocyclic amine molecules are disordered over two crystallographically distinct positions and are diprotonated in order to balance the charge of the anionic layers.