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Boganov, S.E., Egorov, M.P., Faustov, V.I., Krylova, I.V., Nefedov, O.M., Becerra, R. and Walsh, R. (2005) Gas-phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene. Russian Chemical Bulletin, 54 (3). pp. 483-511. ISSN 1066-5285 doi: 10.1007/s11172-005-0285-5
Abstract/Summary
The results of time-resolved gas phase studies of labile germylenes (GeH2 and GeMe2) and dimethylstannylene (SnMe2) reactions reported to date are considered together with data of quantum-chemical investigations of the potential energy surfaces of these systems. Reaction mechanisms are discussed. A comparison of reactivity in the series of carbene analogs, ER2 (E = Si, Ge, Sn, R = H, Me), is made.
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| Item Type | Article |
| URI | https://reading-clone.eprints-hosting.org/id/eprint/11042 |
| Identification Number/DOI | 10.1007/s11172-005-0285-5 |
| Refereed | Yes |
| Divisions | Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry |
| Uncontrolled Keywords | germylene, dimethylgermylene, dimethylstannylene, reaction kinetics, time-resolved, studies, quantum-chemical calculations, RRKM calculations, Arrhenius parameters, thermochemistry, ABSOLUTE RATE CONSTANTS, LASER FLASH-PHOTOLYSIS, QUANTUM-CHEMICAL CALCULATIONS, SILYLENE ADDITION-REACTION, POTENTIAL-ENERGY SURFACE, ARYL-SUBSTITUTED TRIGERMANES, H INSERTION REACTION, TEMPERATURE-DEPENDENCE, AB-INITIO, THERMAL-DECOMPOSITION |
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