Identification, characterisation and quantification of degradation adducts of CyMe4-BTBP

Babra, J. S. (2021) Identification, characterisation and quantification of degradation adducts of CyMe4-BTBP. PhD thesis, University of Reading. doi: 10.48683/1926.00106725

Abstract/Summary

CyMe4-BTBP and CyMe4-BTPhen are ligands planned for use in the selective actinide process (SANEX). The process was devised to extract the minor actinides from the lanthanides found in post-DIAMEX 4M HNO3 raffinate into the organic diluent cyclohexanone or 1-octanol. However, the raffinate is radiotoxic emitting α- and γ-radiation, which in turn propagates the radiolysis of these ligands resulting in degradation products. This thesis outlines the progress towards identifying and characterising the degradation adducts of CyMe4-BTBP in both cyclohexanone and 1-octanol by endeavouring to synthesize the degradation adducts.

Item Type	Thesis (PhD)
URI	https://reading-clone.eprints-hosting.org/id/eprint/106725
Identification Number/DOI	10.48683/1926.00106725
Divisions	Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
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